adding new lectures: 3d eigenstates, rotation, angular momentum

This commit is contained in:
othocaes 2016-03-16 18:05:07 -04:00
parent 677105e073
commit a9a0d33b50
6 changed files with 113 additions and 0 deletions

View File

@ -0,0 +1,29 @@
❙r❭=❙x,y,z❭
with eigenvalue equations
x̂❙r❭ = x❙r❭
ŷ❙r❭ = y❙r❭
ẑ❙r❭ = z❙r❭
An arbitrary state
❙Ψ❭ = ∫∫∫ dx dy dz ❙x,y,z❭❬x,y,z❙Ψ❭
= ∫ d³r ❙r❭ ❬r❙Ψ❭
Understanding a System:
measure Ĥ, L̂², L̂𝓏 → Constitutes a complete set of commuting observables (except spin)
I.E., There is a set of eigenstates that are eigenstates of all three operators.
Ĥ❙E,l,mₗ❭ = E❙E,l,mₗ❭
L̂²❙E,l,mₗ❭ = l(l+1)ħ²❙E,l,mₗ❭
𝓏❙E,l,mₗ❭ = mₗħ❙E,l,mₗ❭
Ĥ must now include angular momentum
L̂²= (r̂×p̂)(r̂×p̂) = (geometric identity) = r̂²p̂ - (r̂⋅p̂) + ιħr̂⋅p̂

View File

@ -0,0 +1,58 @@
Rotational Invariance
𝐩² and 𝐫 are invariant under rotation.
Consider
R̂(dϕ k̂) = 1 - ι/ħ L̂𝓏
❙x - ydϕ,y + xdϕ,z❭ = ❙x,y,z❭ + ∂/∂x ❙ ❭ dϕ + ∂/∂y ❙ ❭ dϕ
= [1 - ι/ħ p𝓍 (-ydϕ)][1 - ι/ħ p𝓎 (xdϕ)] ❙x,y,z❭
= [1 - ι/ħ (x p𝓎 - y p𝓍)dϕ] ❙x,y,z❭
(x p𝓎 - y p𝓍) ≝ L̂𝓏 (angular momentum in z axis)
𝓏 is the z component of L̂ = 𝐫×𝐩̂
Commutation:
[L̂𝓏,p̂𝓏] = [x p𝓎 - y p𝓍,p𝓏]
= (xp𝓎p𝓍 - yp𝓍p𝓍) - (p𝓍xp𝓎 - p𝓍yp𝓍)
= [x,p𝓍]p𝓎 - [y,p𝓍]p𝓍 = [x,p𝓍]p𝓎 = ιħp𝓎
0
[L̂𝓏,p̂𝓍] = ιħp̂𝓎
[L̂𝓏,p̂𝓎] = -ιħp̂𝓎
[L̂𝓏,p̂𝓏] = 0
[L̂𝓏,p̂²] = 0
i.e. the kinetic energy commutes with the L̂𝓏, so one can measure angular momentum and kinetic energy without disturbing the other.
Proof:
[L̂𝓏,p̂²] = [L̂𝓏,p̂𝓍² + p̂𝓎² + p̂𝓏²]
= [L̂𝓏,p̂𝓍²] + [L̂𝓏,p̂𝓎²] + [L̂𝓏,p̂𝓏²]
= p̂𝓍[L̂𝓏,p̂𝓍] + [L̂𝓏,p̂𝓍]p̂𝓍 + p̂𝓎[L̂𝓏,p̂𝓎] + [L̂𝓏,p̂𝓎]p̂𝓎 + p̂𝓏[L̂𝓏,p̂𝓏] + [L̂𝓏,p̂𝓏]p̂𝓏`
= ιħp̂𝓍𝓎 + ιħp̂𝓎𝓍 - ιħp̂𝓎𝓍 - ιħp̂𝓍𝓎 = 0
[L̂𝓏,r̂²] = 0 (homework) → [L̂𝓏,1/r²] = 0
→ [L̂𝓏,V(│r│)] = 0
So,
[L̂𝓏,Ĥ] = 0.
𝓏 is therefore a constant of motion (time-independent)
- Must do work to change?
[L̂²,Ĥ] = 0, so L̂² is also a constant of motion.

View File

@ -0,0 +1,20 @@
Translation Operators
Matrix mechanical expression:
T̂(a𝓍 î) ❙x,y,z❭ = ❙x+a𝓍,y,z❭
T̂(a𝓎 î) ❙x,y,z❭ = ❙x,y+a𝓎,z❭
T̂(a𝓏 î) ❙x,y,z❭ = ❙x,y,z+a𝓏
Position space form:
T(a𝓍 î) = exp(-ι p𝓍 a𝓍/ħ )
Translation operators commute since momentum operators commute.
But, [x̂ᵢ,p̂ⱼ]=ιħδᵢⱼ
T̂(𝐚) = exp(-ι p𝓍 a𝓍/ħ ) exp(-ι p𝓎 a𝓎/ħ ) exp(-ι p𝓏 a𝓏/ħ )
= exp(-ι 𝐩 𝐚/ħ )
❬r❙p̂❙Ψ❭ = ħ/ι ∇ ❬r❙Ψ❭

View File

@ -0,0 +1 @@
../3-14/3d eigenstates

View File

@ -0,0 +1,4 @@
[L̂𝓏,p̂𝓏] = ιħp̂𝓎
[L̂𝓏,p̂𝓍] = -ιħp̂𝓎
[L̂𝓏,p̂𝓏] = 0
[L̂𝓏,p̂²] =

View File

@ -0,0 +1 @@
../3-14/rotational invariance