phy-4600/lecture_notes/3-16/hydrogen atom

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V = E͟_͟Z͟ (?)
r
❬r❙E,l,mₗ❭ ≝ R(𝐫) ≝ U͟(𝐫͟)
r
∂²/∂r² (u/r) + 2/r ∂/∂r U/r
= ∂/∂r (1/r (∂/∂r u) - u/r²) + 2/r ((1/r ∂/∂r u) - u/r²)
= 1/r (∂²/∂r² u) - 2/r^2 ∂/∂r u + 2 u/r³ + 2/r² ∂/∂r u - 2u/r³
= 1/r (∂²/∂r² u)
So,
(-ħ/2m ∂²/∂r² + Veff(│r│)) = V(│r│) + l͟(l͟+͟1͟)ħ͟²͟
2mr²
| ↓ |
Centrifugal
barrier