V = E͟_͟Z͟ (?) r ❬r❙E,l,mₗ❭ ≝ R(𝐫) ≝ U͟(𝐫͟) r ∂²/∂r² (u/r) + 2/r ∂/∂r U/r = ∂/∂r (1/r (∂/∂r u) - u/r²) + 2/r ((1/r ∂/∂r u) - u/r²) = 1/r (∂²/∂r² u) - 2/r^2 ∂/∂r u + 2 u/r³ + 2/r² ∂/∂r u - 2u/r³ = 1/r (∂²/∂r² u) So, (-ħ/2m ∂²/∂r² + Veff(│r│)) = V(│r│) + l͟(l͟+͟1͟)ħ͟²͟ 2mr² | ↓ | Centrifugal barrier