Derivation of Electron States in Hydrogen Atom ━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━ The Hydrogen atom follows the central potential development from the previous lecture. ❬r,θ,φ❙Ψ❭ = R(r)ₑ,ₗ yₗₘ(θ,φ) Rₑₗ(r) = Uₑₗ(r) /r ρ ≡ √⎛8͟m͟ │E│⎞r ⎝ ħ² ⎠ λ = Z͟e͟² √⎛_͟m͟_͟ ⎞ ħ ⎝2│E│⎠ d͟²͟ U - 1͟ l(l+1) + ⎛λ͟ - 1͟⎞U = 0 dρ² ρ² ⎝ρ 4⎠ as ρ→0, U→ρˡ⁺¹ for ρ→∞, d͟²͟ U - 1͟U = 0 dρ² 4 d͟²͟ U - 1͟U = 0 dρ² 4 U(ρ) = A exp(-ρ/2) + B exp(ρ/2) = A exp(-ρ/2) (ρ→∞, B=0) U(ρ) = ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ) d͟ U = (l+1)ρˡ exp(-ρ/2) Fₑₗ(ρ) dρ -½ ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ) + ρˡ⁺¹ exp(-ρ/2) d͟ Fₑₗ(ρ) dρ d͟ U = ⎛l͟+͟1͟ - 1͟ ⎞ U + ρˡ⁺¹ exp(-ρ/2) d͟ F(ρ) dρ ⎝ ρ 2 ⎠ dρ d͟²͟ U = -(l͟+͟1͟) U + ⎛l͟+͟1͟ - 1͟⎞² U dρ² ρ² ⎝ ρ 2⎠ + 2⎛l͟+͟1͟ - 1͟⎞ρˡ⁺¹ exp(-ρ/2) d͟F͟ ⎝ ρ 2⎠ dρ + ρˡ⁺¹ exp(-ρ/2) d͟²͟ F(ρ) dρ² ⎡−͟ħ͟² d² + l͟ (l+1)ħ² - Z͟e͟²⎤Uₑₗ(r) = E Uₑₗ(r) ⎣2m dr² 2mr² r ⎦ ρ = √⎛8͟m͟ │E│⎞r ⎝ ħ² ⎠ ⎛⎞ ⎝⎠