added 3-28 lecture

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caes 2016-03-31 01:44:29 -04:00
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5 changed files with 2756 additions and 49 deletions

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Developed Theory for The Hydrogen Atom

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Theory of the Hydrogen Atom
━━━━━━━━━━━━━━━━━━━━━━━━━━━━
V(𝐫) = -e²/r
For any hydrogenic ion with nuclear charge Z
V(𝐫) = -Ze²/r
Eigenfunctions in spherical coordinates:
Ψₑ﹐ₗ﹐ₘ(r,θ,φ) = Rₑ﹐ₗ(r) Yₗ﹐ₘ(θ,φ) = Uₑ﹐ₗ/r Yₗ﹐ₘ(θ,φ)
Derived from first principles the wave equation of an electron in the
hydrogen atom.
- Start with Dirac Notation
- Replace with known general functions
- transform to eigenvalue equation in position space
- replace pieces with function F and find derivatives
F = ∑ Cₖρ
pic 3 first take had factors that needed to be fixed
- Led to the Laguerre Polynomials
These are infinite, though, so
- Force Laguerre Polynomial solutions to truncate
Derivation
━━━━━━━━━━
Derivation of Electron States in Hydrogen Atom
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
The Hydrogen atom follows the central potential development from the
previous lecture.
❬r,θ,φ❙Ψ❭ = R(r)ₑ,ₗ yₗₘ(θ,φ)
❬r,θ,φ❙Ψ❭ = R(r)ₑ,ₗ yₗₘ(θ,φ)
Rₑₗ(r) = Uₑₗ(r) /r
Rₑₗ(r) = Uₑₗ(r) /r
ρ ≡ √⎛8͟m͟ │E│⎞r
⎝ ħ² ⎠
ρ ≡ √⎛8͟m͟ │E│⎞r
⎝ ħ² ⎠
λ = Z͟e͟² √⎛_͟m͟_͟ ⎞
ħ ⎝2│E│⎠
λ = Z͟e͟² √⎛_͟m͟_͟ ⎞
ħ ⎝2│E│⎠
d͟²͟ U - 1͟ l(l+1) + ⎛λ͟ - 1͟⎞U = 0
dρ² ρ² ⎝ρ 4⎠
@ -56,31 +30,35 @@ Derivation
U(ρ) = A exp(-ρ/2) + B exp(ρ/2) = A exp(-ρ/2)
(ρ→∞, B=0)
U(ρ) = ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ)
U(ρ) = ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ)
d͟ U = (l+1)ρˡ exp(-ρ/2) Fₑₗ(ρ)
d͟ U = (l+1)ρˡ exp(-ρ/2) Fₑₗ(ρ)
dρ
-½ ρˡ⁺¹ exp(-ρ/2) Fₑ﹐ₗ(ρ)
+ ρˡ⁺¹ exp(-ρ/2) d͟ Fₑ﹐ₗ(ρ)
dρ
-½ ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ)
+ ρˡ⁺¹ exp(-ρ/2) d͟ Fₑₗ(ρ)
dρ
d͟ U = ⎛l͟+͟1͟ - 1͟ ⎞ U + ρˡ⁺¹ exp(-ρ/2) d͟ F(ρ)
dρρ 2 ⎠ dρ
d͟²͟ U = -(l͟+͟1͟) U + ⎛l͟+͟1͟ - 1͟⎞² U
dρ² ρ² ⎝ ρ 2⎠
+ 2⎛l͟+͟1͟ - 1͟⎞ρˡ⁺¹ exp(-ρ/2) d͟F͟
ρ 2⎠ dρ
+ ρˡ⁺¹ exp(-ρ/2) d͟²͟ F(ρ)
dρ²
d͟²͟ U = -(l͟+͟1͟) U + ⎛l͟+͟1͟ - 1͟⎞² U
dρ² ρ² ⎝ ρ 2⎠
+ 2⎛l͟+͟1͟ - 1͟⎞ρˡ⁺¹ exp(-ρ/2) d͟F͟
ρ 2⎠ dρ
+ ρˡ⁺¹ exp(-ρ/2) d͟²͟ F(ρ)
dρ²
⎡−͟ħ͟² d² + l͟ (l+1)ħ² - Z͟e͟²⎤Uₑₗ(r) = E Uₑₗ(r)
⎡−͟ħ͟² d² + l͟ (l+1)ħ² - Z͟e͟²⎤Uₑₗ(r) = E Uₑₗ(r)
⎣2m dr² 2mr² r ⎦
ρ = √⎛8͟m͟ │E│⎞r

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Developed Theory for The Hydrogen Atom
Theory of the Hydrogen Atom
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
For any hydrogenic ion with nuclear charge Z
V(𝐫) = -Ze²/r
V(𝐫) = -e²/r
Eigenfunctions in spherical coordinates:
Ψₑₗₘ(r,θ,φ) = Rₑₗ(r) Yₗₘ(θ,φ) = Uₑₗ/r Yₗₘ(θ,φ)
Derived from first principles the wave equation of an electron
in the hydrogen atom.
- Start with Dirac Notation
- transform to eigenvalue equation in position space
Replace with known special quantities
- replace pieces with function F and find derivatives
F = ∑ Cₖρ
pic 3 first take had factors that needed to be fixed
- Led to the Laguerre Polynomials
These are infinite, though, so
- Force Laguerre Polynomial solutions to truncate

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Developed Theory for The Hydrogen Atom
Theory of the Hydrogen Atom
━━━━━━━━━━━━━━━━━━━━━━━━━━━━
For any hydrogenic ion with nuclear charge Z
V(𝐫) = -Ze²/r
V(𝐫) = -e²/r
Eigenfunctions in spherical coordinates:
Ψₑₗₘ(r,θ,φ) = Rₑₗ(r) Yₗₘ(θ,φ) = Uₑₗ/r Yₗₘ(θ,φ)
Derived from first principles the wave equation of an electron in the
hydrogen atom.
- Start with Dirac Notation
- Replace with known general functions
- transform to eigenvalue equation in position space
- replace pieces with function F and find derivatives
F = ∑ Cₖρ
pic 3 first take had factors that needed to be fixed
- Led to the Laguerre Polynomials
These are infinite, though, so
- Force Laguerre Polynomial solutions to truncate