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Developed Theory for The Hydrogen Atom
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Theory of the Hydrogen Atom
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Derivation of Electron States in Hydrogen Atom
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━━━━━━━━━━━━━━━━━━━━━━━━━━━━
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━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
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V(𝐫) = -e²/r
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For any hydrogenic ion with nuclear charge Z
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V(𝐫) = -Ze²/r
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Eigenfunctions in spherical coordinates:
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Ψₑ﹐ₗ﹐ₘ(r,θ,φ) = Rₑ﹐ₗ(r) Yₗ﹐ₘ(θ,φ) = Uₑ﹐ₗ/r Yₗ﹐ₘ(θ,φ)
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Derived from first principles the wave equation of an electron in the
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hydrogen atom.
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- Start with Dirac Notation
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- Replace with known general functions
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- transform to eigenvalue equation in position space
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- replace pieces with function F and find derivatives
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F = ∑ Cₖρᵏ
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pic 3 first take had factors that needed to be fixed
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- Led to the Laguerre Polynomials
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These are infinite, though, so
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- Force Laguerre Polynomial solutions to truncate
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Derivation
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━━━━━━━━━━
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The Hydrogen atom follows the central potential development from the
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The Hydrogen atom follows the central potential development from the
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previous lecture.
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previous lecture.
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❬r,θ,φ❙Ψ❭ = R(r)ₑ,ₗ yₗ﹐ₘ(θ,φ)
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❬r,θ,φ❙Ψ❭ = R(r)ₑ,ₗ yₗₘ(θ,φ)
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Rₑ﹐ₗ(r) = Uₑ﹐ₗ(r) /r
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Rₑₗ(r) = Uₑₗ(r) /r
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ρ ≡ √⎛8͟m͟ │E│⎞r
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ρ ≡ √⎛8͟m͟ │E│⎞r
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⎝ ħ² ⎠
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⎝ ħ² ⎠
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λ = Z͟e͟² √⎛_͟m͟_͟ ⎞
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λ = Z͟e͟² √⎛_͟m͟_͟ ⎞
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ħ ⎝2│E│⎠
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ħ ⎝2│E│⎠
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d͟²͟ U - 1͟ l(l+1) + ⎛λ͟ - 1͟⎞U = 0
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d͟²͟ U - 1͟ l(l+1) + ⎛λ͟ - 1͟⎞U = 0
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dρ² ρ² ⎝ρ 4⎠
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dρ² ρ² ⎝ρ 4⎠
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@ -56,31 +30,35 @@ Derivation
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U(ρ) = A exp(-ρ/2) + B exp(ρ/2) = A exp(-ρ/2)
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U(ρ) = A exp(-ρ/2) + B exp(ρ/2) = A exp(-ρ/2)
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(ρ→∞, B=0)
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(ρ→∞, B=0)
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U(ρ) = ρˡ⁺¹ exp(-ρ/2) Fₑ﹐ₗ(ρ)
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U(ρ) = ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ)
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d͟ U = (l+1)ρˡ exp(-ρ/2) Fₑ﹐ₗ(ρ)
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d͟ U = (l+1)ρˡ exp(-ρ/2) Fₑₗ(ρ)
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dρ
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dρ
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-½ ρˡ⁺¹ exp(-ρ/2) Fₑ﹐ₗ(ρ)
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+ ρˡ⁺¹ exp(-ρ/2) d͟ Fₑ﹐ₗ(ρ)
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-½ ρˡ⁺¹ exp(-ρ/2) Fₑₗ(ρ)
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dρ
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+ ρˡ⁺¹ exp(-ρ/2) d͟ Fₑₗ(ρ)
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dρ
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d͟ U = ⎛l͟+͟1͟ - 1͟ ⎞ U + ρˡ⁺¹ exp(-ρ/2) d͟ F(ρ)
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d͟ U = ⎛l͟+͟1͟ - 1͟ ⎞ U + ρˡ⁺¹ exp(-ρ/2) d͟ F(ρ)
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dρ ⎝ ρ 2 ⎠ dρ
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dρ ⎝ ρ 2 ⎠ dρ
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d͟²͟ U = -(l͟+͟1͟) U + ⎛l͟+͟1͟ - 1͟⎞² U
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d͟²͟ U = -(l͟+͟1͟) U + ⎛l͟+͟1͟ - 1͟⎞² U
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dρ² ρ² ⎝ ρ 2⎠
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dρ² ρ² ⎝ ρ 2⎠
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+ 2⎛l͟+͟1͟ - 1͟⎞ρˡ⁺¹ exp(-ρ/2) d͟F͟
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⎝ ρ 2⎠ dρ
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+ 2⎛l͟+͟1͟ - 1͟⎞ρˡ⁺¹ exp(-ρ/2) d͟F͟
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+ ρˡ⁺¹ exp(-ρ/2) d͟²͟ F(ρ)
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⎝ ρ 2⎠ dρ
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dρ²
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+ ρˡ⁺¹ exp(-ρ/2) d͟²͟ F(ρ)
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dρ²
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⎡−͟ħ͟² d² + l͟ (l+1)ħ² - Z͟e͟²⎤Uₑ﹐ₗ(r) = E Uₑ﹐ₗ(r)
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⎡−͟ħ͟² d² + l͟ (l+1)ħ² - Z͟e͟²⎤Uₑₗ(r) = E Uₑₗ(r)
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⎣2m dr² 2mr² r ⎦
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⎣2m dr² 2mr² r ⎦
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ρ = √⎛8͟m͟ │E│⎞r
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ρ = √⎛8͟m͟ │E│⎞r
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@ -1 +1,32 @@
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Developed Theory for The Hydrogen Atom
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Developed Theory for The Hydrogen Atom
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Theory of the Hydrogen Atom
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━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
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For any hydrogenic ion with nuclear charge Z
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V(𝐫) = -Ze²/r
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V(𝐫) = -e²/r
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Eigenfunctions in spherical coordinates:
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Ψₑₗₘ(r,θ,φ) = Rₑₗ(r) Yₗₘ(θ,φ) = Uₑₗ/r Yₗₘ(θ,φ)
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Derived from first principles the wave equation of an electron
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in the hydrogen atom.
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- Start with Dirac Notation
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- transform to eigenvalue equation in position space
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Replace with known special quantities
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- replace pieces with function F and find derivatives
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F = ∑ Cₖρᵏ
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pic 3 first take had factors that needed to be fixed
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- Led to the Laguerre Polynomials
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These are infinite, though, so
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- Force Laguerre Polynomial solutions to truncate
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2672
lecture_notes/3-28/overview.ps
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2672
lecture_notes/3-28/overview.ps
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lecture_notes/3-28/overview.txt
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lecture_notes/3-28/overview.txt
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@ -0,0 +1,27 @@
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Developed Theory for The Hydrogen Atom
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Theory of the Hydrogen Atom
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━━━━━━━━━━━━━━━━━━━━━━━━━━━━
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For any hydrogenic ion with nuclear charge Z
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V(𝐫) = -Ze²/r
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V(𝐫) = -e²/r
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Eigenfunctions in spherical coordinates:
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Ψₑₗₘ(r,θ,φ) = Rₑₗ(r) Yₗₘ(θ,φ) = Uₑₗ/r Yₗₘ(θ,φ)
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Derived from first principles the wave equation of an electron in the
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hydrogen atom.
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- Start with Dirac Notation
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- Replace with known general functions
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- transform to eigenvalue equation in position space
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- replace pieces with function F and find derivatives
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F = ∑ Cₖρᵏ
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pic 3 first take had factors that needed to be fixed
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- Led to the Laguerre Polynomials
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These are infinite, though, so
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- Force Laguerre Polynomial solutions to truncate
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